期刊
JOURNAL OF MATERIALS CHEMISTRY
卷 13, 期 1, 页码 102-105出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b206445f
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The dispersion capacity of MoO3 on the surface of muscovite powder was studied by X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD) techniques. The results indicated that MoO3 can disperse onto the surface of a support as a sub-monolayer. The dispersion capacity was 5.88 mg MoO3 (g muscovite)(-1), or 3.24 Mo atoms nm(-2). The diffusing process of MoO3 on muscovite wafer was investigated by means of Synchrotron Radiation excited Total-reflection X-Ray Fluorescence spectroscopy (SR-TXRF). A stripe of MoO3 on the muscovite wafer was used as the diffusion source. After thermal treatment in air or dry N-2, MoO3 diffuses onto the surface of muscovite and forms a sub-monolayer. Sublimation of MoO3 was also detected during the diffusion process. The diffusion rate in two heating atmospheres differed significantly. The diffusion rate of MoO3 on muscovite in dry N-2 was greater than that in air. A possible explanation of the phenomena is that surface diffusion onto the muscovite surface plays a more important role in the process than transportation via gas phase during the diffusion of MoO3.
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