4.8 Article

Direct fabrication of mesoporous carbons using in-situ polymerized silica gel networks as a template

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CARBON
卷 41, 期 8, 页码 1525-1532

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PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0008-6223(03)00072-1

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porous carbon; carbonization; BET surface area; porosity

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Mesoporous carbons were synthesized by in-situ polymerized silica gel networks as a template. The co-condensation of carbon precursor (sucrose) and silica precursor (sodium silicate) followed by heat treatment generated a carbon/silica nanocomposite. After etching the silica template, mesoporous carbons were obtained. Under optimum synthesis conditions a mesoporous carbon with a high surface area of >800 m(2)/g and a narrow pore size distribution centered at 3 nm was produced. The three-dimensionally interconnected silica structures effectively functioned as the template for the porous carbon materials. (C) 2003 Elsevier Science Ltd. All rights reserved.

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