期刊
POLYHEDRON
卷 22, 期 1, 页码 177-188出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0277-5387(02)01268-8
关键词
octamolybdate subunits; hydrothermal synthesis; mixed metal oxides; hydrothermal reactions
The hydrothermal reactions of MoO3, an appropriate Cu(II) source, and a dipodal nitrogen donor ligand yielded a series of bimetallic oxides [Cu2Mo4O13(3,3'-bipy)(2)].H2O(1.H2O), [CuMo4O13(Hdipyreth)] (2), and [Cu(dpp)](2)[Cu-2(alpha-Mo8O26)(dpp)(2)].2H(2)O (3.2H(2)O). (3,3'-bipy = 3,3'-bipyridine; dipyreth = 1,2-bis(2-pyridyl)ethylene; dpp = 4,4'-trimethylenedipyridine). The materials 1.H2O and 2 are constructed from octamolybdate clusters linked through copper-ligand subunits, while 3.2H(2)O exhibits fused octamolybdate building blocks in a two-dimensional molybdate chain. (C) 2002 Elsevier Science Ltd. All rights reserved.
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