期刊
AUSTRALIAN JOURNAL OF CHEMISTRY
卷 57, 期 12, 页码 1161-1164出版社
CSIRO PUBLISHING
DOI: 10.1071/CH04117
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Following photodissociation of vinyl chloride seeded in a He supersonic jet at 193 nm, rotationally resolved infrared emission of HCl ( v) are recorded to yield nascent rotational and vibrational distributions. Preliminary results show that the rotational distribution of HCl free from rotational quenching deviates slightly from Boltzmann-type distribution and agrees well with trajectory calculations; a portion of the low-J component observed previously in a flow system is attributed to quenching. The implications for photodissociation dynamics are discussed.
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