期刊
CATALYSIS TODAY
卷 234, 期 -, 页码 91-99出版社
ELSEVIER
DOI: 10.1016/j.cattod.2014.01.028
关键词
Solid acid; Carbide; Renewable diesel; 2-Methylfuran; Mesityl oxide
资金
- Natural Science Foundation of China [21106143, 21277140]
- 100-talent project of Dalian Institute of Chemical Physics (DICP)
- Independent Innovation Foundation of State Key Laboratory of Catalysis of DICP [R201113]
For the first time, the alkylation of 2-methylfuran with mesityl oxide was carried out over a series of solid acid catalysts. Among the investigated candidates, Nafion-212 resin exhibited the highest catalytic efficiency and good stability, which can be rationalized by the higher acid strength of this catalyst. The hydrodeoxygenation (HDO) of the alkylation products of 2-methylfuran with mesityl oxide was also studied. Ni-Mo2C/SiO2 and Ni-W2C/SiO2 were firstly used for the HDO of biomass derived oxygenates and demonstrated excellent catalytic performance for the conversion of the alkylation products to alkanes. Compared with Ni-W2C/SiO2, Ni-Mo2C/SiO2 exhibited higher selectivity to diesel range alkanes. Over the Ni-Mo2C/SiO2 catalyst, high carbon yield of diesel range alkanes (77%) could be achieved by the HDO of the alkylation products of 2-methylfuran and mesityl oxide at 573 K and 6.0 MPa H-2. This value is evidently higher than those obtained over noble metal catalysts and Ni-WxC/AC under the same reaction conditions. (C) 2014 Elsevier B.V. All rights reserved.
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