期刊
CATALYSIS TODAY
卷 217, 期 -, 页码 76-79出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.cattod.2013.06.013
关键词
Template condensation; Zinc(II) 1,3,5-triazapentadienato complex; Catalytic activity; Henry reaction
资金
- Foundation for Science and Technology (FCT), Portugal [PEst-OE/QUI/UI0100/2011]
- Baku State University, Azerbaijan
- Moscow State University, Russia
Template condensation of CCl3CN and ammonia on zinc(II) (used as acetate) afforded, in one step, bis(2,4-bis(trichloromethyl)-1,3,5-triazapentadienato)-zinc(II) 1, which was characterized by elemental analysis, ESI-MS, IR and X-ray single-crystal analysis. The complex 1 was shown to be an effective catalyst in the nitroaldol (Henry) reaction, providing high yields (up to 99%) and good diastereoselectivities (threo/erythro up to 3: 1) at ambient conditions. Crown Copyright (C) 2013 Published by Elsevier B. V. All rights reserved.
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