期刊
CATALYSIS TODAY
卷 185, 期 1, 页码 99-103出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.cattod.2011.10.030
关键词
Diesel soot combustion; Thermogravimetery; Apparent activation energy
Soot combustion performance of supported Ag (Ag/TiO2 and Ag/CeO2) and K (K/TiO2 and K/CeO2) catalysts under tight and loose contact conditions was evaluated by thermogravimetric analysis (TG) and the determination of the apparent activation energy as a function of soot conversion. The soot combustion performance strongly depended on the active species and contact conditions. The soot combustion proceeded by catalytic and non-catalytic combustion processes, depending on the contact conditions and the active species. Almost all the soot was catalytically combusted over Ag and K supported catalysts when they were tightly contacted with the soot, and Ag was more active catalytic species for soot oxidation than K. Under the loose contact condition, the supported K catalyst was superior to the supported Ag catalysts in the fraction of catalytically combusted soot and propagation of the combustion to the non-contact soot. Therefore, the supported K catalyst showed higher performance than the supported Ag catalyst for the removal of the majority of soot under the loose contact condition. (C) 2011 Elsevier B.V. All rights reserved.
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