期刊
CATALYSIS TODAY
卷 180, 期 1, 页码 111-116出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.cattod.2011.07.035
关键词
Partial oxidation of methane; Pt/CeZrO2/Al2O3 catalysts; Syngas; Hydrogen production
资金
- CAPES
- CNPq
In this study, we evaluated the effect of ceria-zirconia content on the performance of Pt/ x% CeZrO2/Al2O3 (x = 0-40 wt.%) during partial oxidation of methane. X-ray diffraction results indicated that, for samples containing 10 and 20 wt.% of CeZrO2, there was the formation of a homogeneous solid solution between ceria and zirconia. On the other hand, for Pt/30% CeZrO2/Al2O3, there was the formation of a ceria rich phase and a zirconia rich phase whereas a ceria rich phase and an isolated zirconia phase were detected for Pt/40% CeZrO2/Al2O3. Catalytic tests showed that Pt/Al2O3 exhibited a significant deactivation, while Pt/10% CeZrO2/Al2O3 and Pt/20% CeZrO2/Al2O3 practically did not loose their activity after 24 h. A deactivation was detected for Pt/30% CeZrO2/Al2O3 and Pt/40% CeZrO2/Al2O3. The higher stability of the Pt/10% CeZrO2/Al2O3 and Pt/20% CeZrO2/Al2O3 catalysts was attributed to the high reducibility and consequently the high oxygen mobility of the homogeneous solid solution formed, which promoted the mechanism of carbon removal from the metallic particle. (C) 2011 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据