期刊
CATALYSIS TODAY
卷 164, 期 1, 页码 23-27出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.cattod.2010.11.015
关键词
Metal organic framework; Bi-organic ligand; Spillover; Hydrogen adsorption; Fuel cell
A bi-organic-ligand type of Zn-2(bdc)(2)dabco MOFs was synthesized and characterized in the present work. The catalytic properties of Pt/AC and Pd/AC were studied for hydrogen spillover in Zn-2(bdc)(2)dabco modified by 5.0 wt.% of catalyst. The hydrogen adsorption capacity of modified Zn-2(bdc)(2)dabco was significantly enhanced up to 3.35 wt.% by using the secondary spillover with carbon bridges measured at 1.5 bar and 77 K. Moreover, the prepared MOFs were also identified using FE-SEM, HR-TEM, XRD, XANES/EXAFS, and BET N-2 adsorption isotherms techniques. (C) 2010 Elsevier B. V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据