期刊
CATALYSIS TODAY
卷 168, 期 1, 页码 71-79出版社
ELSEVIER
DOI: 10.1016/j.cattod.2011.03.045
关键词
H-ZSM-5; Hierarchical zeolites; Methanol-to-gasoline; Fe-ZSM-5; Selective catalytic reduction
An H-ZSM-5 zeolite sample consisting of large particles (5-15 mu m) was synthesized and base treated using sodium hydroxide, guanidinium hydroxide and guanidinium carbonate to create a hierarchical pore system. In the case of sodium hydroxide as demetallation agent a high degree of mesoporosity was achieved and with guanidinium hydroxide, mesoporosity was observed after prolonged treatment. All samples were tested in the methanol-to-gasoline (MTG) reaction and iron-impregnated samples were tested for selective catalytic reduction of NO with ammonia (SCR). In the MTG reaction an improved catalyst lifetime was observed which has been correlated to the creation of mesopores. In the SCR reaction improved NO conversion was observed for all base treated samples. In accordance with spectroscopic results this has been attributed to a higher abundance of active and dispersed Fe sites in the base treated samples. All samples were characterized by a multitude of experimental techniques including physisorption measurements, electron microscopy and spectroscopic methods. (C) 2011 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据