期刊
DESIGNED MONOMERS AND POLYMERS
卷 7, 期 4, 页码 391-397出版社
TAYLOR & FRANCIS LTD
DOI: 10.1163/1568555041475275
关键词
NMRP initiators; Mn(OAc)(3); alkoxyamines; nitroxide radicals
O-substituted hydroxylamines which are known to initiate and promote nitroxide-mediated radical polymerization were synthesized in high yield by a novel and facile synthetic approach. Using the favorable Mn(OAc)(3) as electron transfer agent in the in situ generation of benzylic radicals and their trapping by nitroxide radicals provides a new powerful and more economic way to the desired alkoxyamine initiators for this controlled, living radical polymerization. TEMPO, TIPNO and the protected tris-hydroxy derivative of TIPNO were used to synthesize the appropriate alkoxyamines.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据