期刊
RESEARCH ON CHEMICAL INTERMEDIATES
卷 30, 期 7-8, 页码 713-721出版社
SPRINGER
DOI: 10.1163/1568567041856918
关键词
Sonochemical reaction; ultrasonic effect; hydroxyl radical; numerical calculation; rate constant
In this study, a KI aqueous solution or Methyl Orange (MO) aqueous solution was irradiated by an ultrasonic wave under the same experimental condition. The rates of oxidation of KI and MO by OH radicals differed by an order of magnitude. When the consumption of OH radicals by chemical reactions with species other than KI or MO is taken into account, numerical analysis of chemical kinetics model yields the same generation rate of OH radicals by the action of an ultrasonic wave for the experiments of KI and MO solutions.
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