期刊
CHEMICAL SOCIETY REVIEWS
卷 33, 期 5, 页码 267-273出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b307652k
关键词
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In this tutorial review applications of alkoxyamines as C-radical precursors for the conduction of tin-free radical reactions are presented. These processes are controlled by the Persistent Radical Effect. A brief introduction on the Persistent Radical Effect is provided. In addition, the use of microwave irradiation to conduct thermal radical reactions is discussed. Finally, the use of alkoxyamines as initiators/mediators for the controlled/living radical polymerization is highlighted.
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