期刊
CATALYSIS LETTERS
卷 144, 期 12, 页码 2005-2011出版社
SPRINGER
DOI: 10.1007/s10562-014-1337-y
关键词
Heterogeneous catalysis; Reaction intermediates; C-H bond activation; Phenols; Metal-support interaction; Biomass conversion; Hydrodeoxygenation
资金
- National Science Foundation [EPSCoR0814361]
- US Department of Energy [DE-FG36GO88064]
- Oklahoma Bioenergy Center
- CAPES (Coordenacao de Aperfeicoamento de Pessoal de Ensino Superior)
The hydrodeoxygenation of m-cresol has been studied on SiO2- and ZrO2-supported Pd catalysts. Regardless of metal dispersion, the latter exhibit greatly enhanced selectivity to toluene. This remarkable support effect can be explained in terms of a mechanism that involves a keto-intermediate tautomer favored by oxophilic sites on the support. .
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