期刊
CATALYSIS LETTERS
卷 144, 期 7, 页码 1159-1163出版社
SPRINGER
DOI: 10.1007/s10562-014-1264-y
关键词
Lignin; Homogeneous catalysis; KOH; beta-O-4 cleavage
资金
- National Natural Science Foundation of China [51176184]
- National Basic Research Program of China [2012CB215302]
- National High-tech RD Program [2012AA101808-2]
- Fundamental Research Funds for the Central Universities [WK2090130009]
Base, especially KOH, can be used in place of xantphos for the Ruthenium-complex-catalyzed C-O bond cleavage of beta-O-4 lignin model compounds. In the presence of KOH, RuHCl(CO)(PPh3)(3) and Ru(H)(2)(CO)(PPh3)(3) show the best catalytic effect among several ruthenium-complexes studied. Base, especially KOH, can be used in place of xantphos for the Ruthenium-complex-catalyzed C-O bond cleavage of beta-O-4 lignin model compounds. In the presence of KOH, RuHCl(CO)(PPh3)(3) and Ru(H)(2)(CO)(PPh3)(3) show the best catalytic effect among several ruthenium-complexes studied.
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