期刊
CATALYSIS LETTERS
卷 145, 期 1, 页码 458-467出版社
SPRINGER
DOI: 10.1007/s10562-014-1449-4
关键词
Catalysis; C-H bond activation; C-C coupling; Homogeneous catalysis
The past two decades have witnessed explosive growth in the field of catalytic C-H activation. While this reactivity is typically associated with second- and third-row transition metals, first-row transition metals are also capable of catalyzing these reactions. C-H activation reactions can be further divided into ones where the C-H activation occurs with a low-valent metal and those where the activation occurs with a high-valent metal. This review will summarize advances in the area of high-valent Co(III)- and Ni(II)-catalyzed C-H activation with particular emphasis paid to how these catalysts compare their second- and third-row congeners.
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