4.5 Article

Synthesis of a Novel Nano-Sized Pt/ZnO Catalyst for Water Gas Shift Reaction in Medium Temperature Application

期刊

CATALYSIS LETTERS
卷 142, 期 9, 页码 1075-1081

出版社

SPRINGER
DOI: 10.1007/s10562-012-0868-3

关键词

Pt/ZnO catalyst; Water gas shift reaction; Medium temperature

资金

  1. National Research Foundation of Korea (NRF)
  2. Ministry of Education, Science and Technology [2010-0002521]
  3. Korea Institute of Energy Research
  4. National Research Foundation of Korea [2010-0002521] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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A novel nano-sized Pt/ZnO catalyst has been prepared by impregnating 1 wt% Pt on a nano-sized ZnO supports, with spherical and rod-type morphology and tested for the water gas shift reaction at a gas hourly space velocity of 9,583 h(-1). The Pt/ZnO catalyst with spherical ZnO morphology exhibited an almost thermodynamic equilibrium CO conversion value of 70 % at 400 A degrees C with 100 % CO2 selectivity. The high activity/stability of the catalyst is due to a good interfacial contact between Pt and ZnO. A novel nano-sized Pt/ZnO catalyst has been prepared by impregnating 1 wt% Pt on a nano-sized ZnO supports, with spherical and rod-type morphology and tested for the water gas shift reaction at a gas hourly space velocity of 9,583 h(-1). The Pt/ZnO catalyst with spherical ZnO morphology exhibited an almost thermodynamic equilibrium CO conversion value of 70 % at 400 A degrees C with 100 % CO2 selectivity. The high activity/stability of the catalyst is due to a good interfacial contact between Pt and ZnO.

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