期刊
CATALYSIS LETTERS
卷 143, 期 2, 页码 169-175出版社
SPRINGER
DOI: 10.1007/s10562-012-0932-z
关键词
Heterogeneous catalysis; Ferrier rearrangement; 2-Deoxy sugars; O-glycosides
资金
- MIUR, National Project Approccio ecocompatibile all'intensificazione di processo nella sintesi organica
Layered alpha-zirconium sulfophenylphosphonate-methanphosphonate is a solid acid catalyst that catalyzes Ferrier rearrangement from d-glycals and alcoholic nucleophiles under mild reaction conditions in short time and good yields. Notably, the combination of alpha-zirconium sulfophenylphosphonate-methanphosphonate and lithium bromide change the regioselectivity of this process affording 2-deoxy sugars in good yields.
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