期刊
CATALYSIS LETTERS
卷 142, 期 1, 页码 138-142出版社
SPRINGER
DOI: 10.1007/s10562-011-0732-x
关键词
Supported catalyst; MCM-41; Hydrothiolation; Phosphine rhodium complex; Heterogeneous catalysis
资金
- National Natural Science Foundation of China [20862008]
- Natural Science Foundation of Jiangxi Province in China [2008GQH0034, 2010GZH0062]
A novel diphosphino-functionalized MCM-41 anchored rhodium complex [MCM-41-2P-RhCl(PPh3)] was conveniently synthesized by the reaction of diphosphino-functionalized MCM-41 (MCM-41-2P) with RhCl(PPh3)(3). It was found that this rhodium complex is an efficient catalyst for the hydrothiolation of terminal alkynes with thiols and can be recovered and recycled by a simple filtration of the reaction solution and used for at least ten consecutive trials without any decreases in activity.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据