4.5 Article

Structure Effects on Pyridine Hydrogenation over Pt(111) and Pt(100) Studied with Sum Frequency Generation Vibrational Spectroscopy

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CATALYSIS LETTERS
卷 137, 期 3-4, 页码 118-122

出版社

SPRINGER
DOI: 10.1007/s10562-010-0353-9

关键词

Pyridine hydrogenation; Pt(111); Pt(100); Catalysis; Nanoparticles

资金

  1. Director, Office of Energy Research, Office of Basic Energy Sciences
  2. Materials Sciences Division of the U.S. Department of Energy [DE-AC02-05CH11231]

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Sum frequency generation vibrational spectroscopy was applied in-situ during pyridine hydrogenation (10 Torr pyridine and 100 Torr hydrogen) over two well-defined platinum single crystals, Pt(100) and Pt(111). The surface reaction intermediates were clarified. Pyridine adsorbs to both crystals vertically, with in-tact aromatic ring. Over Pt(100) 1,4-dihydropyridine bound through the nitrogen was observed as a reaction intermediate, while over Pt(111) this was not detected. Upon heating the crystals from 300 to 350 K, the pyridine ring lies down flat on the catalyst surfaces. Over Pt(111) a tilted piperidine product is bound to the surface. Ring-cracking products were not observed over either surface.

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