期刊
CATALYSIS LETTERS
卷 129, 期 3-4, 页码 499-506出版社
SPRINGER
DOI: 10.1007/s10562-008-9831-8
关键词
Oxidation of cyclohexene; Selenite doped MCM-41; 2-Acetoxycyclohexanol
资金
- National Basic Research Program of China [2008CB617514]
- National Natural Science Foundation of China [20863009]
- Yunnan Province [2007B018M, 2008CD065]
Liquid phase oxidation of cyclohexene was carried out under mild reaction conditions over selenite doped MCM-41 using aqueous hydrogen peroxide as oxidant and acetic acid as solvent. The major products of the reaction were 2-acetoxycyclohexanol and a small amount of 1,2-cyclohexanediol. The catalyst exhibited very high substrate conversion (similar to 100%) and good product (2-acetoxycyclohexanol) selectivity (81%) and it can be reused with almost the same activity. The catalyst was characterized by a combination of various physicochemical techniques, such as N-2 physisorption, TEM, X-ray diffraction and FT-IR.
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