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卷 123, 期 1-2, 页码 46-50出版社
SPRINGER
DOI: 10.1007/s10562-007-9379-z
关键词
Co(salen); oxygen oxidations; cobalt catalysts; CO(2) expanded solvents
This work correlates the basicity of various axial ligands (AL), including triethylamine, methylimidazole, pyridine, acetonitrile or water, with the efficacy of catalytic oxidation of 2,6-di-tert-butylphenol by Co(salen)(AL) in CO(2)-expanded methylene chloride. Further, Co(salen)(AL)O(2) abstracts hydrogen atoms from substrates of high to intermediate reactivity (BDECH <= similar to 90 kcal/mol).
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