4.5 Article

Perovskite-type Oxide LaMnO3: An Efficient and Recyclable Heterogeneous Catalyst for the Wet Aerobic Oxidation of Lignin to Aromatic Aldehydes

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CATALYSIS LETTERS
卷 126, 期 1-2, 页码 106-111

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SPRINGER
DOI: 10.1007/s10562-008-9588-0

关键词

Perovskite-type oxide LaMnO3; Catalytic wet aerobic oxidation; Lignin; Aromatic aldehydes; Activity; Reusability

资金

  1. Natural Science Foundation of China [50776035, U0733001]
  2. Foundation of Scientific Research for Universities [20070561038]
  3. Ministry of Education of China [IRT0552]
  4. Ministry of Science and Technology of China [2007AA05Z408, 2007BAD34B01]

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The perovskite-type oxide catalyst LaMnO3 prepared by the sol-gel method was found to be an efficient heterogeneous and recyclable catalyst for the wet aerobic oxidation of lignin to aromatic aldehydes. The lignin conversion rate and the yield of each aromatic aldehyde were enhanced significantly by the catalytic process as compared with the non-catalyzed process. Moreover, the activity, specific surface area and perovskite-type structure of the LaMnO3 catalyst remained nearly unchanged after five successive recycles of catalytic reactions.

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