期刊
CATALYSIS LETTERS
卷 124, 期 3-4, 页码 413-417出版社
SPRINGER
DOI: 10.1007/s10562-008-9494-5
关键词
nanoenzyme; supermolecule; thiolated-cyclodextrin; gold nanoparticles; enzyme mimic
资金
- Natural Science Foundation of China [20534030, 20471023]
- National Basic Research Program [2007CB808006]
- Innovative Research Team in University [IRT0422]
An artificial nanozyme model was developed by the supramolecular complexation of a beta-cyclodextrin-modified gold nanoparticle and metal catalytic centers. The cyclodextrin-based monolayer was first constructed on the surface of gold nanoparticle by using the thiol modified cyclodextrin, subsequently the cyclodextrin-modified gold nanoparticle was utilized as a backbone to install metal catalytic centers by supramolecular assembly of the copper complex of triethylnetetramine-adamantane and beta-cyclodextrin receptors immobilized on the surface of gold nanospheres via hydrophobic interaction. The catalytic behaviors of beta-cyclodextrin-modified gold nanoparticles with adjacent multi-metal catalytic centers were investigated as an esterase mimic. Strong hydrolase activities for catalyzing the cleavage of an active ester 4,4'-dinitrodiphenyl carbonate (DNDPC) were observed. A detailed kinetic study on nanozyme-catalyzed hydrolysis of ester DNDPC has been described.
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