期刊
CATALYSIS COMMUNICATIONS
卷 31, 期 -, 页码 32-36出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.catcom.2012.11.003
关键词
Alkanes; Homogeneous catalysis; Hydrogen peroxide; Hydrocarboxylation; Hydroperoxidation; Iron complexes
资金
- Russian Foundation for Basic Research [12-03-00084-a]
- Fundacao para a Ciencia e a Tecnologia, FCT [PTDC/QUI-QUI/102150/2008, PEst-OE/QUI/UI0100/2011, SFRH/BPD/34926/2007]
- Fundação para a Ciência e a Tecnologia [PTDC/QUI-QUI/102150/2008] Funding Source: FCT
Ferrocene in an unexpected emploi: alkanes can be efficiently oxygenated by H2O2 in the presence of catalytic amounts of this well-known organometallic compound in combination with pyrazine-2-carboxylic acid or 2,2'-bipyridine. Saturated hydrocarbons, RH, are also transformed into carboxylic acids, RCOOH, when reacted with the ferrocene/CO/S2O82-/H2O system in acetonitrile solution. (C) 2012 Elsevier B.V. All rights reserved.
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