期刊
CATALYSIS COMMUNICATIONS
卷 24, 期 -, 页码 44-47出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.catcom.2012.03.013
关键词
Methanol; Propylene; ZSM-5; Boron; Isomorphous substitution; Methanol to propylene (MTP)
资金
- Research Fund for the Doctoral Programme of Higher Education [20100071110008]
- 863 programme [2009AA033701]
- Shanghai Huayi Group Co. Ltd.
A series of boron isomorphously framework-substituted ZSM-5 (B-x-Al-ZSM-5, Si/Al = 200, B/Al = X) were synthesized and used to selectively transform methanol to propylene (MTP). The catalytic stability can be significantly influenced by B incorporation. In comparison with the conventional ZSM-5, the B-1-Al-ZSM-5 catalyst afforded a 7-time-long catalytic life under a space velocity of WHSV 1.8 h(-1) (700 h for B-1-Al-ZSM-5 and 100 h for ZSM-5, respectively). The enhancement of catalytic stability can be attributed to the increase of weak acid sites on the ZSM-5 catalysts. (C) 2012 Elsevier B.V. All rights reserved.
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