期刊
CATALYSIS COMMUNICATIONS
卷 17, 期 -, 页码 29-33出版社
ELSEVIER
DOI: 10.1016/j.catcom.2011.10.006
关键词
Gold; Hollow silica sphere; Mesoporous; Palladium; Phenol hydrogenation
资金
- National Natural Science Foundation of China [20673040, 20876062, 21076089]
- Ministry of Science and Technology of China [2009AA05Z119]
- Fundamental Research Funds for the Central Universities
- Department of Science and Technology of Guangdong Province [2004A11004003]
A high-performance, gold-promoted Pd catalyst with mesoporous hollow silica spheres as support, PdAu/MHSS, was prepared using an impregnation-reduction approach. The catalyst showed 10 times higher activity than commercial Pd/C catalyst and 6 times higher activity than Pd/MHSS catalyst. The conversion of phenol was 100% within 30 min of reaction at 80 degrees C. The catalyst was characterized by XRD, XPS, and TEM, which revealed that its high performance may result from both the high dispersion of active components on the MHSS, caused by the addition of gold, and the interaction between palladium and gold. (C) 2011 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据