期刊
CATALYSIS COMMUNICATIONS
卷 18, 期 -, 页码 110-114出版社
ELSEVIER
DOI: 10.1016/j.catcom.2011.11.033
关键词
Hierarchical zeolite; n-Heptane; Ethylene; Propylene; Cracking
资金
- National Natural Science Foundation of China [20990221]
A series of hierarchical porous zeolites (ZSM-5-ZRP-1) was synthesized by adding different contents of ZRP-1 to the procedure of hydrothermal synthesis of ZSM-5. The prepared samples were characterized by using N-2 adsorption-desorption, XRD, SEM, TEM, NH3-TPD, Py-FTIR and investigated in cracking of n-heptane. The results indicate that physicochemical properties and catalytic performances of ZSM-5-ZRP-1 samples are quite different from those of HZSM-5 or ZRP-1. ZSM-5-ZRP-1 samples have a lot of mesopores and suitable amount of B + L acid sites as well as higher L/B ratio compared with HZSM-5 or ZRP-1, and also show medium acid amount and strength. These lead to a higher selectivity of olefins (ethylene plus propylene) obtained on it. (C) 2011 Elsevier B.V. All rights reserved.
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