期刊
CATALYSIS COMMUNICATIONS
卷 20, 期 -, 页码 80-84出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.catcom.2012.01.007
关键词
Hydrodeoxygenation; Methyl hexadecanoate; Biofuels; Ni/HZSM-5 catalyst
资金
- National Natural Science Foundation of China [51076157]
- Key Natural Science Fund of China [51036006]
- Chinese Academy of Sciences [KSCX2-YW-G-063]
Ni/HZSM-5 catalysts with different Ni loadings were prepared by impregnation method, and their catalytic performance was evaluated in the hydrodeoxygenation (HDO) upgrading of the model reactant methyl hexadecanoate (MHD) to liquid alkane fuels. The physicochemical properties of the catalysts were characterized by XRD, SEM, NH3-TPD, and BET. Ni loadings were obviously influenced by the acidity, and thus significantly affected their catalytic performance. Over 7 wt.% Ni/HZSM-5 catalyst, MHD conversion of more than 90% and total liquid C-5-C-16 hydrocarbon selectivity of 83% were obtained under the optimum reaction condition, possibly due to the synergistic effect of metal Ni and acid HZSM-5. (C) 2012 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据