期刊
CATALYSIS COMMUNICATIONS
卷 29, 期 -, 页码 166-169出版社
ELSEVIER
DOI: 10.1016/j.catcom.2012.10.003
关键词
Intercalated materials; Nanosheets; Tantalotungstate; Manganese; Visible-light photocatalysis
资金
- NNSF of China [50872037, 21003055, 21103054]
- NSF of Fujian Province [2010J01040]
Manganese-intercalated layered tantalotungstates have been assembled by tantalotungstate nanosheets with manganese ions via an exfoliation-restacking route. The as-prepared nanohybrids are mesoporous with specific surface areas more than 36 m(2)/g and the mesopores are originated from the house-of-cards-type stacking of the intercalated crystallites. Introducing manganese ions into the intersheeted regions allows the nanohybrids to exhibit distinct spectral responses in visible-light region with band gaps less than 2.54 eV. The porous nanohybrids exhibit high photocatalytic activities in the degradation of methylene blue under visible-light irradiation. (C) 2012 Elsevier B.V. All rights reserved.
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