期刊
CATALYSIS COMMUNICATIONS
卷 16, 期 1, 页码 86-89出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.catcom.2011.09.008
关键词
Ni-B amorphous alloy catalyst; Nickel hydrazine complex; Ultrasonic assistance; Hydrogenation; Glucose
资金
- Natural Science Foundation of Hebei Province [B2009000675]
Fine Ni-B amorphous alloy catalysts with uniform particles were prepared by means of chemical reduction of nickel hydrazine (N(2)H(4)) complex by BH(4)(-) in aqueous solution with ultrasonic assistance. During glucose hydrogenation. the as-prepared Ni-B catalyst exhibited much higher activity than the conventional Ni-B catalysts obtained via direct reduction of Ni(2+) by BH(4)(-). and Raney Ni. The higher activity could be attributed to both higher dispersion of Ni active sites and electronic effect. The nickel hydrazine complex was found to retard and prevent an abrupt formation and agglomeration of Ni-B catalysts during the catalysts preparation. It was also found that the ultrasound plays a positive role. (C) 2011 Elsevier B.V. All rights reserved.
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