4.6 Article

Platinum catalysts supported on hydrothermally stable mesoporous aluminosilicate for the catalytic oxidation of polycyclic aromatic hydrocarbons (PAHs)

期刊

CATALYSIS COMMUNICATIONS
卷 11, 期 13, 页码 1068-1071

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ELSEVIER SCIENCE BV
DOI: 10.1016/j.catcom.2010.04.017

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Polycyclic aromatic hydrocarbons (PAHs); Naphthalene; Catalytic oxidation; Hydrothermally stable mesoporous aluminosilicate; MCM-41; Platinum

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Catalytic oxidation of polycyclic aromatic hydrocarbons (PAHs) was studied over platinum catalysts supported on the hydrothermally stable mesoporous aluminosilicate (SM-41). Naphthalene was chosen as a model reactant of PAHs, due to the simplest and the least toxic PAHs. Zeolite seeds crystallization method was used for synthesis of SM-41. Pt/SM-41 catalyst showed higher activity than Pt/MCM-41 for catalytic oxidation of naphthalene in the presence of 10 vol.% water vapor. Hydrothermal stability and hydrophobicity of Pt/SM-41 must be beneficial for the catalytic oxidation of naphthalene in the presence of water vapor. (C) 2010 Elsevier B.V. All rights reserved.

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