期刊
CATALYSIS COMMUNICATIONS
卷 10, 期 14, 页码 1791-1795出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.catcom.2009.05.019
关键词
Hydroformylation; Reductive amination; Hydroaminomethylation; Tandem catalysis; Ruthenium catalysts; Carbon dioxide; Reverse-water-gas-shift reaction
Use of carbon dioxide as a reactant instead of toxic carbon monoxide in the hydroaminomethylation reaction sequence is demonstrated for the first time. The present Ru-3(CO)(12)-catalyzed one-pot protocol includes reverse-water-gas-shift (RWGS) reaction, hydroformylation reaction and reductive amination which finally leads to secondary and tertiary amine. The influence of various reaction parameters including the effects of catalytic promotors and phase-transfer-catalysts has been investigated. Finally, an optimum reaction conditions were found by suppressing the major side products to have a variety of amines in excellent yields (up to 98%). (c) 2009 Elsevier B.V. All rights reserved.
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