期刊
CATALYSIS COMMUNICATIONS
卷 10, 期 12, 页码 1599-1603出版社
ELSEVIER
DOI: 10.1016/j.catcom.2009.04.026
关键词
Selective oxidation; 2-Methoxy-5-methyl-1,4-benzoquinone; Cu/MCM-41; 4-Methylanisole
资金
- National Basic Research Program of China [2008CB617514]
- National Natural Science Foundation of China [20863009]
- Natural Science Foundation of Yunnan Province [2007B018 M, 2008CD065]
- Education Department Foundation of Yunnan Province [07211110]
- Specialized Research Fund for the Doctoral Program of Higher Education
The oxidation of 4-methylanisole (MA) to 2-methoxy-5-methyl-1,4-benzoquinone (MMBQ) in acetic acid using H2O2 as oxidant over Cu/MCM-41 was studied for the first time. Efficient conversion rate of MA (81%) and reasonable selectivity of MMBQ (78%) was obtained. Fast hot catalyst filtration experiment proved that Cu/MCM-41 acted as a heterogeneous catalyst and it can be reused a number of times with almost the same activity. (C) 2009 Elsevier B.V. All rights reserved.
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