期刊
CATALYSIS COMMUNICATIONS
卷 9, 期 1, 页码 45-50出版社
ELSEVIER
DOI: 10.1016/j.catcom.2007.04.026
关键词
green oxidation reactions; phenols; arenes; quinones; heteropolyoxotungstates; hydrogen peroxide
The fused polycyclic systems (phenantrene, anthracene, naphthalene), naphthols (I and 2), phenol, polyalkyl-substituted phenols (hydroquinone, catechol, m-methoxyphenol, o-cresol) and toluene were catalytically oxidized with H2O2 Using a lacunary phosphotungstic acid derivative whose formula is Na8H[Delta PW9O34]center dot 19H(2)O (Delta-PW9). The reaction was carried out under homogeneous conditions of catalysis at 55 degrees C, using acetone as solvent. Under such conditions, the naphthols were selectively oxidized in the presence of phenols. It was observed that the conversion to quinones from naphthols was higher than that from polycyclic fused systems. Considering the performance of the above mentioned reactions, the 2-naphthol oxidation was selected to test the complex heteropoly-tungstate catalysts. These catalysts are derived from the coupling of two fragments [PW9O34] (lacunar, Keggin-like, Delta-PW9) of general formula K-10[(PW9O34)(2)M-4(H2O)(2)]center dot 20H(2)O in which M stands for Co, Zn and Mn divalent ions. The reaction was evaluated by using acetone and/or acetonitrile solvents at their reflux temperatures. Under such conditions, the P-naphthol was selectively oxidized to 1,2-naphthoquinone. The catalytic selectivity and the influence of the heteropolytungstate metallic clusters on the primary lacunar phase were also comparatively analyzed. (c) 2007 Elsevier B.V. All rights reserved.
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