期刊
CATALYSIS COMMUNICATIONS
卷 9, 期 14, 页码 2345-2348出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.catcom.2008.05.025
关键词
Pd/C catalyst; regioselective hydrogenation; p-cyclohexylphenol; p-phenylphenol
资金
- Liaoning Natural Science Foundation, China [20052188]
Regioselective hydrogenation of p-phenyl phenol (p-PP) to p-cyclohexyl phenol (p-CP) was performed over 10 wt.% Pd/C catalyst in THF solvent. The selectivity of p-CP was up to 92.3% at 413 K under 3.5 MPa with 100% conversion of p-PP. The desired product could be easily separated from the reaction mixture by washing with aqueous NaOH following extraction by toluene. The reaction mechanism was discussed. (C) 2008 Elsevier B.V. All rights reserved.
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