4.7 Article

First stable 7,7,8,8-tetraaryl-o-quinodimethane: isolation, X-ray structure, electrochromic response of 9,10-bis(dianisylmethylene)-9,10-dihydrophenanthrene

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CHEMICAL COMMUNICATIONS
卷 -, 期 18, 页码 2076-2077

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ROYAL SOC CHEMISTRY
DOI: 10.1039/b405837b

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Oxidative cyclization of 2,2'-bis(dianisylethenyl) biphenyl yielded the dicationic salt of phenanthrene-9,10-diylbis( dianisylmethylium), which in turn afforded the severely congested title molecule as the first stable tetraaryl-o-quinodimethane derivative upon reduction.

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