期刊
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
卷 6, 期 22, 页码 5250-5255出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b409848j
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The copper-modified ZSM-5 zeolites, prepared by ion-exchange in an aqueous solution of Cu(CH3COO)(2) and subjected to different treatments were studied by FTIR spectroscopy using molecular hydrogen adsorbed at 77 K and at room temperature as a probe. For reduced and calcined CuZSM-5 samples broad range IR spectra were measured and discussed in detail. At least two different Cu+ sites in CuZSM-5 reduced with CO were distinguished using molecular hydrogen as a probe. It was established that the copper adsorption sites which strongly perturb hydrogen molecules are Cu+ ions that also strongly adsorb dinitrogen molecules. For reduced CuZSM-5 adsorption isoterms of H-2, N-2 and CO were measured. A comparison of the amounts of strongly adsorbed H-2, N-2 and CO has also been made. The amounts of adsorbed molecules decreased in the following sequence: CO>N-2>H-2. Based both on the results of FTIR studies and measurements of amounts of adsorbed H-2, N-2 and CO it was concluded that there are different Cu+ sites which differ in the strength of interaction with adsorbed molecules probably due to different localization in the zeolite framework.
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