期刊
JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN
卷 73, 期 1, 页码 33-35出版社
PHYSICAL SOC JAPAN
DOI: 10.1143/JPSJ.73.33
关键词
chemical physics; homochirality; enantiometric excess; stereochemistry; rate equation
The nonlinear autocatalysis of the chiral substance is shown to achieve homochirality in a closed system, if the back reaction is included. Asymmetry in the concentration of two enantiomers or enantiometric excess increases due to the nonlinear autocatalysis. Furthermore, when the back reaction is taken into account, the reactant supplied by the decomposition of the enantiomers is recycled to produce more of the dominant enantiomer, and eventually homochirality is established.
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