期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 2, 期 11, 页码 1643-1646出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b403568b
关键词
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Starting from a vinylepoxide, a short and practical synthesis of D-erythro-sphingosine is described. The key transformations are a regioselective opening of the vinylepoxide and an E-selective cross-metathesis, affording the target molecule in 5 steps and 51% overall yield.
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