期刊
PHYSICS OF THE SOLID STATE
卷 46, 期 4, 页码 644-648出版社
PLEIADES PUBLISHING INC
DOI: 10.1134/1.1711441
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The effect of modifying detonation nanodiamond additives on the stress-strain properties of polymer nanocomposites is investigated using polysiloxane polyblock copolymers as an example. It is shown that the formation of a physical network of supramolecular structures (due to self-organization initiated by force fields of highly active nanoparticles) can lead to an increase in the physicomechanical parameters in the range of small strains (up to 100%) without changing the chain microstructure. The use of composites involving fillers of the H type (with a high surface activity) and the L type (with a low surface activity) provides a maximum efficiency of interaction of the force fields induced by supramolecular structural units. The force interaction results in a more efficient supramolecular organization of the polymer and ensures a synergetic increase in the physicomechanical parameters with the use of L-H fillers. (C) 2004 MAIK Nauka / Interperiodica.
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