期刊
ARKIVOC
卷 -, 期 -, 页码 10-35出版社
ARKAT USA INC
DOI: 10.3998/ark.5550190.0005.e02
关键词
alpha-aminoalkyl radical; intramolecular radical additions; pyrrolidines; homolytic cleavage; translocation; PET; SmI2-promoted reductions
The intramolecular additions of C-centered neutral alpha-aminoalkyl radicals onto suitably positioned C-C double bonds provide a ready access into functionalized carbocycles and heterocycles. This strategy offers considerable versatility in the selection of starting materials since a number of methods using different functional groups and reagents are available for Phi-aminoalkyl radical generation. This review covers the recent progress in this field.
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