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Free radical-mediated acylation and carboxylation reactions

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ADVANCED SYNTHESIS & CATALYSIS
卷 346, 期 1, 页码 19-32

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WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200303128

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acylation; aldehydes; carboxylation; C-C coupling; ketones; radicals

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Radical acylations to prepare carbonyl compounds are described and focus on indirect acylation approaches using sulfonyl oxime ethers under tin-mediated and tin-free conditions. The efficiency of carboxylic acid derivatives as carbonyl group radical acceptors in radical acylation and carboxylation reactions is discussed.

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