期刊
ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY
卷 11, 期 -, 页码 213-216出版社
SPRINGER
DOI: 10.1007/s10450-005-5925-4
关键词
adsorption; chromatography; gravimetry; VOC; zeolites; Henry constant
Both the inverse gas chromatographic method and the dynamic gravimetric-calorimetric method were tested in order to determine the Henry constant for toluene on a Na-faujasite type zeolite. We used the pulse technique for the chromatographic method and a system generating low concentration of VOC in a helium flow for the gravimetric technique. The experimental determinations of the Henry constants for toluene were achieved in two different temperature ranges (from 363 to 548 K for gravimetry and from 548 to 673 K for chromatography). The results presented in this paper show the complementarity of two different techniques for the Henry constants determination. The Henry constants obtained with the two techniques at 548 K differ from 8%.
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