In this paper, the on-chip generated mercury microelectrode for heavy metal ion detection has been presented. A mercury droplet (similar to150 mum in diameter) is on-chip generated to form a microelectrode through the mercury microfluidics control. The mercury microelectrode is used to electrochemically detect the heavy metal ions. The sample solutions with different concentration of heavy metal ions (Pb2+ and Cd2+) have been successfully detected on the mercury droplet microelectrode using the square wave stripping voltammetry.
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