期刊
PURE AND APPLIED CHEMISTRY
卷 77, 期 1, 页码 339-344出版社
WALTER DE GRUYTER GMBH
DOI: 10.1351/pac200577010339
关键词
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A biocatalytic approach has been developed to synthesize conducting polyaniline (PANI) nanoparticles. The method involves the formation of nanocomposites of PANI and poly(acrylic acid) (PAA) by polymerizing aniline (AN)-camphorsulfonic acid (CSA) macromonomer (AN/CSA) using a biocatalyst in the presence of template PAA. The second step involves the separation of PANI polymers from PAA and CSA in the nanocomposites. The formation of PANI nanoparticles by this two-step approach is studied by transmission electron microscopy (TEM). High-resolution solution C-13 NMR and UV/visible spectroscopic techniques have been used to characterize the formation of conducting PANI chains by the enzymatic method.
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