期刊
RADIOCHIMICA ACTA
卷 93, 期 12, 页码 733-739出版社
WALTER DE GRUYTER GMBH
DOI: 10.1524/ract.2005.93.12.733
关键词
Am; Cm; Eu; EDTA; high ionic strength; thermodynamics; laser fluorescence spectroscopy
The complexation of Am3+, Cm3+ and Eu3+ with EDTA has been studied at an ionic strength of 6.60 mol kg(-1) (NaClO4) and pcH 3.60 in the temperature range of 0 to 60 degrees C with a solvent extraction technique. The complex M(EDTA)was formed with stability constant values (log beta(101)) at 25 degrees C between 15.9 and 16.1 which increased with increasing temperature. The complex formation enthalpies have been obtained from the temperature dependence of the stability constants. The large positive enthalpy and entropy changes are attributed to the considerably reduced water activity at such high ionic strength resulting in large positive contributions from the dehydration of the trivalent metal ions as compared to the smaller negative contributions from the M3+-EDTA(4-) bonding interaction. The nature of the species of the EuEDTA complex formed at 6.60 mol kg(-1) (NaClO4) and pcH >= 3.60 was studied by time-resolved laser fluorescence spectroscopy and lifetime measurements. Between pcH 3.60 and 7.0, Eu(EDTA)(H2O)(3)(-) was formed while at pcH 9.0, Eu(OH)(EDTA)(H2O)(2) (2-) was present.
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