期刊
CARBON
卷 68, 期 -, 页码 185-194出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2013.10.079
关键词
-
资金
- National Natural Science Foundation of China [21274043]
A series of nitrogen-doped porous carbons are prepared through KOH activation of a nonporous nitrogen-enriched carbon which is synthesized by pyrolysis of the polymerized ethylenediamine and carbon tetrachloride. The porosity and nitrogen content of the nitrogen-doped porous carbons depend strongly on the weight ratio of KOH/carbon. As the weight ratio of KOH/carbon increases from 0.5 to 2, the specific surface area increases from 521 to 1913 m(2) g(-1), while the nitrogen content decreases from 10.8 to 1.1 wt.%. The nitrogen-doped porous carbon prepared with a moderate KOH/carbon weight ratio of 1, which possesses a balanced specific surface area (1463 m(2) g(-1)) and nitrogen content (3.3 wt.%), exhibits the largest specific capacitance of 363 F g(-1) at a current density of 0.1 A g(-1) in 1 M H2SO4 aqueous electrolyte, attributed to the co-contribution of double-layer capacitance and pseudocapacitance. Moreover, it shows excellent rate capability (182 F g(-1) remained at 20 A g(-1)) and good cycling stability (97% capacitance retention over 5000 cycles), making it a promising electrode material for supercapacitors. (C) 2013 Elsevier Ltd. All rights reserved.
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