期刊
CARBON
卷 74, 期 -, 页码 333-345出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2014.03.041
关键词
-
资金
- NSF [EEC-0813570]
- National Science Foundation [DBI 9413969]
Hydrothermal stability of carbon based acid catalysts synthesized by sulfonating carbohydrates pyrolyzed at moderate temperatures (300-600 degrees C) has been reported previously. To test the effect of carbon structure on hydrothermal stability, we produced catalysts by dry pyrolysis at 350 degrees C and 450 degrees C or by hydrothermal carbonization, followed by sulfonation with fuming sulfuric acid, as well as by direct sulfonation of glucose. The catalysts were characterized by BET, titration, Raman spectroscopy, TGA, XPS, reaction testing, and C-13 solid state NMR. Catalysts were hydrothermally treated and then analyzed for sulfur retention and catalytic activity. The lower temperature carbon catalysts showed the best stability, however all showed significant activity loss. Solid state NMR of materials made from C-13-glucose was used to characterize the structural details in an attempt to correlate functional groups to hydrothermal stability of catalyst active sites. Structural models generated from NMR data showed that the most stable catalysts contained a significant fraction of furan rings and hardly any polycondensed aromatic rings. (C) 2014 Elsevier Ltd. All rights reserved.
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