期刊
CARBON
卷 72, 期 -, 页码 387-392出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2014.02.030
关键词
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资金
- Chinese Ministry of Science and Technology [2010CB934202, 2013CB934500]
- National Science Foundation of China [11174333, 91223204]
- Chinese Academy of Sciences (CAS)
Recently, we have developed a catalyst-free and direct growth approach for nanographene on various substrates by a remote-plasma assisted chemical vapor deposition. A two-step growth strategy for separately controlling the nucleation and subsequent edge growth was further developed for growing graphene sheets with adjusted nuclei density and large domain size of 500 nm. The key for tuning the growth mode from nucleation to edge growth is the growth temperature; at a specific growth temperature (similar to 510-545 degrees C), only edge growth is available while the nucleation can be largely suppressed. This fine tuning of growth process yields a continuous polycrystalline graphene film with domain size of similar to 150 nm. This domain size is controllable in this tunable growth to thus giving more freedom to control the graphene film properties. (C) 2014 Elsevier Ltd. All rights reserved.
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